Hi, Aimee!
I just cruised the B and B reviews at Video Fitness, and you might want to do the same. Overall, the reviews are good, but I'm not sure that it's quite what you're looking for. It appears that the only chest work is in the form of 5 sets of pushups. It does seem that it's a well balanced upper and lower body video, however.
Do you have PS CST from Cathe? It is her PS series that really helped me get the strength and definition I was looking for. You might also want to think about her Express 6 pack. There is 1 video that is just cardio and chest work ( You wouldn't have to get them all. You could just get that one video if you wanted. ) Cathe often recommends for people who are having trouble with one particular muscle group throw in some extra work for that group one day a week. So if you're doing 5 days of workouts, say 3 cardio and 2 strength, on a cardio day when you haven't just done weights the day before and won't be doing them the next day, you throw in work on the trouble group. Does that make sense?
I hope this helps!
Erin